Adsorption of Selenium Using Bagasse Fly Ash     

Kailas L. Wasewar  Basheshwar Prasad  Sekhararao Gulipalli 《洁净——土壤、空气、水》2009,37(7):534-543

The present work involves the study of Se(IV) adsorption onto bagasse fly ash. The adsorbents were coated with a ferric chloride solution for the effective removal of selenium. The physico‐chemical characterization of the adsorbent was carried out using standard methods, e. g., proximate analysis, scanning electron microscopy, Fourier transform infrared spectroscopy, thermo‐gravimetric analysis and differential thermal analysis. Batch experiments were carried out to determine the effect of various parameters such as adsorbent dose, initial pH, contact time, and temperature on the adsorption process. Results obtained from these studies were analyzed using various kinetic models and isotherms. Se(IV) adsorption onto adsorbent was high at low pH values, and decreased with an increase in initial pH. A temperature study showed that the uptake of Se(IV) was greatest at 293 K, within the temperature range studied. The parameters of pseudo first order, pseudo second order, and Weber‐Morris intra‐particle kinetic models were determined. Equilibrium isotherms were analyzed using Langmuir, Freundlich, and Temkin isotherms. Error analyses were also carried out using hybrid fractional error function and Marquardt's percent standard deviation.  相似文献   

Removal of Selenium by Adsorption onto Granular Activated Carbon (GAC) and Powdered Activated Carbon (PAC)     

Kailas L. Wasewar  Basheshwar Prasad  Sekhararao Gulipalli 《洁净——土壤、空气、水》2009,37(11):872-883

The present work involves the study of Se(IV) adsorption onto granular activated carbon (GAC) and powdered activated carbon (PAC). The adsorbents are coated with ferric chloride solution for the effective removal of selenium. The physico-chemical characterization of the adsorbents is carried out using standard methods, e. g., proximate analysis, scanning electron microscopy (SEM), fourier transform infrared spectroscopy (FTIR), thermo-gravimetric (TGA) and differential thermal analysis (DTA), etc. The FTIR spectra of the GAC and PAC indicate the presence of various types of functional groups, e. g., free and hydrogen bonded OH groups, silanol groups (Si-OH), alkenes, and CO group stretching from aldehydes and ketones on the surface of adsorbents. Batch experiments are carried out to determine the effect of various factors such as adsorbent dose (w), initial pH, contact time (t), and temperature (T) on the adsorption process. The optimum GAC and PAC dosage is found to be 10 g/L and 8 g/L, respectively, for Se(IV) removal with C₀ = 100 mg/L. The percent removal of Se(IV) increases with increasing adsorbent concentration, while removal per unit weight of adsorbent increases with decreasing adsorbent concentration. Se(IV) adsorption onto both the GAC and PAC adsorbents is high at low pH values, and decreases with increased initial pH. The results obtained are analyzed by various kinetic models. The parameters of pseudo-first order, pseudo-second order kinetics, and Weber-Morris intra particle kinetics are determined. It is seen that the sorption kinetics of Se(IV) onto GAC and PAC can be best represented by the pseudo-second order kinetic model.  相似文献   

四川拉拉铁氧化物铜金矿床（IOCG）形成的矿相学证据   总被引：6，自引：0，他引：6  

朱志敏  曾令熙  周家云  罗丽萍  陈家彪  沈冰 《高校地质学报》2009,15(4):485

四川拉拉铜矿是我国西南重要的大型铜矿,并且共（伴）生丰富的金—钼—钴—稀土—铁可供综合利用。系统的矿相学研究表明,矿石矿物主要为热液磁铁矿、黄铜矿、黄铁矿、白铁矿和辉钼矿;矿床围岩蚀变种类较多,主要有黑云母化、硅化、碳酸盐化、钠长石化、钾长石化、磷灰石化、阳起石化、萤石化等;矿石结构包括自形- 半自形- 它形晶粒结构、交代残余结构、包含结构和枝状结构,矿石构造包括浸染状构造、条带状构造、脉状- 网脉状构造和角砾状构造;载铜矿物主要为黄铜矿,钴主要赋存于黄铁矿和白铁矿中,钼赋存于辉钼矿中,金主要以自然金或含银自然金形式赋存于黄铜矿、黄铁矿和叶碲铋矿中;磁铁矿中钛含量低,矿石中硫含量低,罕见铅锌硫化物矿物。因此,拉拉铜矿应属于典型的铁氧化物铜金矿床。  相似文献   

贵州锦丰（烂泥沟）金矿床含砷黄铁矿和脉石英及其包裹体的微量元素特征   总被引：5，自引：0，他引：5  

胡瑛  陈懋弘  董庆吉  黄庆文 《高校地质学报》2009,15(4):506

贵州锦丰（烂泥沟）金矿是滇黔桂“金三角”目前已探明最大的卡林型金矿床。含砷黄铁矿是该矿床最主要的载金矿物,硅化及石英脉是最显著的热液蚀变类型。本文采用高精度电感耦合等离子质谱（ICP-MS）对含砷黄铁矿和脉石英及其包裹体的微量元素进行了测试,结果表明含砷黄铁矿富亲硫元素,并相对于围岩和上部地壳均强烈富集;亏损V,Sr 及高场强元素。同生黄铁矿也具有类似的特征。脉石英除亲石元素含量高以外,还表现为亲硫元素以及Mo,Bi 含量较高。但与上部地壳相比,绝大部分元素贫化。相应包裹体的微量元素含量普遍低于单矿物,但变化特征一致。结合矿物和包裹体的稀土元素分析,发现脉石英和含砷黄铁矿及其包裹体均表现为HFSE明显亏损,Th/La,Nb/La 比值小于1,说明成矿流体为富Cl 的流体。含砷黄铁矿及其包裹体中Co/Ni 比值远小于1,反映成矿温度较低,推测成矿流体主要来源于以沉积建造水为主的盆地流体。  相似文献   

基于PCA-GEP算法的边坡稳定性预测   总被引：5，自引：1，他引：4  

谷琼  蔡之华  朱莉  黄波 《岩土力学》2009,30(3):757-761

提出一种基于主成分分析的基因表达式程序设计算法,并将其用于边坡稳定性预测。该算法先采用主成分分析法对样本数据进行预处理,有效地减少预测模型的输入量,消除输入数据间的相关性,再将得到的新样本数据输入基因表达式,构建边坡稳定性的预测模型。利用该预测模型对82个危险圆弧破坏边坡实例中的71个实例进行学习,对另外11个实例进行预测,取得了较好的效果。在保留传统的以误差值作为评判模型优劣标准的同时,引入AIC信息准则法,分别对v-SVR算法和GA-BP网络算法和PCA-GEP算法三种预测模型进行比较分析,结果表明,运用该算法可以获得更优的预测模型,其预测结果比v-SVR算法和GA-BP网络等其他算法得到的结果具有更高的预测精度。工程实例计算表明,该方法是合理、可行的。  相似文献   

公路隧道局部塌方洞段的围岩稳定性评价   总被引：2，自引：0，他引：2  

马亢  徐进  吴赛钢  张爱辉 《岩土力学》2009,30(10):2955-2960

结合某公路隧道工程,以现场地质调查和监测资料为基础,在结构面发育且可能发生大规模塌方的围岩洞段,根据现场实际统计的优势结构面产状,采用关键块体理论、非连续变形方法（DDA）首先确定围岩主要的失稳破坏模式,然后运用连续介质分析程序FLAC,在DDA方法确定的围岩实际变形破坏塌方形态的基础上进行计算分析,评价围岩的整体稳定性及加固措施的有效性。分析表明,围岩破坏的主要模式为受结构面控制的局部块体的失稳,工程开挖后围岩不会发生大变形,这与实际情况基本一致,为安全施工提供了保证。采用非连续变形方法和连续介质计算相结合的分析方法对隧道工程塌方稳定性进行研究,取得了较好的效果,研究方法和经验可为类似工程参考并借鉴。  相似文献   

灰色GM(1,1)模型和Verhulst模型在喀斯特地区耕地预测中的应用——以毕节生态试验区为例     

杜江  安裕伦  袁士聪 《中国岩溶》2009,28(4):426-431

毕节生态试验区是典型的喀斯特地区,人口密度大,生态环境脆弱,水土流失严重,耕地保护尤为重要。本文以毕节地区1998—2006年常用耕地面积统计数据为基础,分别利用灰色GM(1,1)模型和Verhulst模型对该喀斯特地区常用耕地面积变化进行预测。预测结果表明,GM(1,1)模型和Verhulst模型都揭示了毕节地区常用耕地面积在未来几年呈逐年递减的趋势。但是通过模拟精度验证,研究区耕地面积原始数据变化曲线呈S型,就灰色GM(1,1)模型与Verhulst模型模拟预测结果相比较,对于原始数据的模拟,GM(1,1)模型预测精度较高,而Verhulst模型更适合研究区未来几年耕地面积变化的预测。该研究结果可为区域合理利用土地资源、编制土地利用规划和耕地保护提供依据。   相似文献   

Comprehensive precursor anomaly research based on earthquake corresponding relevancy spectrum     

Haitao Wang  Qiong Wang  Lanlan Tang Lanzhou Base of Institute of Earthquake Science  China Earthquake Administration  Lanzhou  China Earthquake Administration of Xinjiang Uygur Autonomous Region  Urumqi  China 《地震学报(英文版)》2009,(6):675-681

With the aim to the quantification of anomaly identification and extraction for observed or analyzed records, we present two statistical methods of earthquake corresponding relevancy spectrum(ECRS)and sliding mean relevancy (SMR).With ECRS method,we can obtain the abnormal confidence attribute of data in different value ranges.Based on the relevancy spectrum in different studied time-intervals,we convert the original time sequence into relevancy time sequence, and can obtain the SMR time series by using the...  相似文献   

Lethal toxicity of industrial detergent on bottom dwelling sentinels     

L. I. N. EZEMONYE  D. F. OGELEKA  F. E. OKIEIMEN 《国际泥沙研究》2009,24(4):479-483

We used fresh and brackish water shrimp （Desmoscaris trispinosa and Palaemonetes africanus）, in sediment bioassays to assess the toxicity of an industrial detergent containing high levels of anionic surfactant （linear alkylbenzene sulphonate （LAS））. The Organization for Economic Cooperation and Development （OECD）, # 218 direct sediment toxicity assessment was employed. The organisms were exposed to different concentrations （31.25, 62.5, 125,250 and 500 mg/kg） of the chemical （Neatex） in replicate treatments. Percentage mortality was measured as the ecological endpoint. Mean mortality and estimated lethal concentration LCso values varied with species type, concentration and exposure duration. The statistical variation in the observed mean mortality of the test organisms in the chemical and the control treatment shows that mortality may be induced by the effect of the chemicals. The lethal concentration （LCso） was significantly different at levels ofp 〈 0.05 for the fresh and brackish water experiments. Consequently, assessment of water and sediment quality as a result of chemical pollutants was necessary for protecting some of the more sensitive benthic invertebrates representing the major proportion of the diet of many species in the Niger Delta ecological zone.  相似文献   

佛开高速九江大桥模态测试与分析     

王立新  杜鹏  李小华 《华南地震》2009,29(3):9-16

对主跨为160m的预应力砼变截面连续梁桥佛开高速九江大桥进行了理论与实验模态分析．首先介绍了环境激励条件下现场模态测试布置及过程,利用随机子空间法（SSI）进行了桥梁模态参数识别．建立了桥梁有限元模型．并对理论和实验模态分析结果进行了比较和讨论。实验与有限元计算结果在竖向模态频率及振型上总体吻合较好。测试结果可以为有限元模型修正提供依据：模态测试与有限元分析相结合．可以为桥梁长期健康监测和损伤评估提供较可靠的基准模型。  相似文献